The present study deals with the comparison of pure polymer and nanocomposite thin film coating towards corrosion of mild steel in 1 N H2SO4. Clay nanoparticles were incorporated in the vinylidene polymer and thus obtained polymeric nanocomposite were coated on the mild steel coupons by dipping method, at different thickness. Potentiodynamic polarization tests were conducted on the prepared samples using 1 N H2SO4. The test results showed that the mild steel coupons coated by polyvinylidene fluoride and nanoclay top coating resulted in excellent corrosion resistance. Almost cent percent corrosion resistance has been achieved with a combination of 0.5% PVDF and 10% clay w.r.t polymer and also 10% PVDF with 5% clay. The former combination is much more economical and may prove to be of much importance in practical usage. The presence of clay improves barrier properties by increasing its adherence and blocking the pin-holes in the PVDF film.